Applications of graphene oxide (GO) in oily wastewater treatment: Recent developments, challenges, and opportunities.

The treatment of oily wastewater has become a serious environmental challenge, for which graphene oxide has emerged as a promising material in solving the problem. The ever-growing utilization of graphene oxide (GO) in the treatment of oily wastewater necessitates a constant review. This review article employs a comprehensive literature survey methodology, systematically examining peer-reviewed articles, focusing on, but not entirely limited to, the last five years. Major databases such as EBSCOhost, Scopus, ScienceDirect, Web of Science and Google Scholar were searched using specific keywords related to GO and oily wastewater treatment. The inclusion criteria focused on studies that specifically address the application, efficiency, and mechanisms of GO in treating oily wastewater. The data extracted from these sources were then synthesized to highlight the most important developments, challenges, and prospects in this field. As far as oily wastewater treatment is concerned, the majority of the studies revolve around the use of GO in mitigating fouling in membrane processes, improving the stability, capacity and reusability of sorbents, and enhancing photodegradation by minimizing charge recombination.

Ag-CuO-Decorated Ceramic Membranes for Effective Treatment of Oily Wastewater.

Although ultrafiltration is a reliable method for separating oily wastewater, the process is limited by problems of low flux and membrane fouling. In this study, for the first time, commercial TiO2/ZrO2 ceramic membranes modified with silver-functionalized copper oxide (Ag-CuO) nanoparticles are reported for the improved separation performance of emulsified oil. Ag-CuO nanoparticles were synthesized via hydrothermal technique and dip-coated onto commercial membranes at varying concentrations (0.1, 0.5, and 1.0 wt.%). The prepared membranes were further examined to understand the improvements in oil-water separation due to Ag-CuO coating. All modified ceramic membranes exhibited higher hydrophilicity and decreased porosity. Additionally, the permeate flux, oil rejection, and antifouling performance of the Ag-CuO-coated membranes were more significantly improved than the pristine commercial membrane. The 0.5 wt.% modified membrane exhibited a 30% higher water flux (303.63 L m-2 h-1) and better oil rejection efficiency (97.8%) for oil/water separation among the modified membranes. After several separation cycles, the 0.5 wt.% Ag-CuO-modified membranes showed a constant permeate flux with an excellent oil rejection of >95% compared with the unmodified membrane. Moreover, the corrosion resistance of the coated membrane against acid, alkali, actual seawater, and oily wastewater was remarkable. Thus, the Ag-CuO-modified ceramic membranes are promising for oil separation applications due to their high flux, enhanced oil rejection, better antifouling characteristics, and good stability.

Valorization of date palm leaves for adsorptive remediation of 2,4-dichlorophenoxyacetic acid herbicide polluted agricultural runoff.

Alarming rates of water contamination by toxic herbicides have prompted the need and attention for easy, efficient, and affordable treatment options with a touch of circular economy aspects. This study valorized date palm leaf (DPL) wastes into a valuable adsorbent for remediating agricultural wastewater polluted with 2,4-Dichlorophenoxyacetic acid (2,4-DPA) herbicide. The DPL precursor was modified with H2SO4 treatment and both biomass samples were characterized by various analytical techniques. Acid treatment modified the morphology, thermal, and textural properties of the final product (TDPL) while maintaining the structure and surface chemistry intact. Simulated wastewaters containing 2,4-DPA were subsequently treated using TDPL as an adsorbent. Optimum adsorption conditions of pH 2, dosage 0.95 g/L, shaking speed 200 rpm, time 120 min, and temperature 30 °C showed a good herbicide removal efficiency in the range of 55.1-72.6% for different initial feed concentrations (50-250 mg/L). Experimental kinetic data were better represented by the pseudo-second-order model, while the Freundlich isotherm was reliable in describing the equilibrium behavior of the adsorption system. Further, the thermodynamic analysis revealed that the adsorption occurred spontaneously, favorably, and exothermically. Plausible sorption mechanism involved electrostatic interactions, weak van der Waals forces, hydrogen bonds, and π-π interactions between the participating phases. Conspicuously, TDPL application to real-world situations of treating actual herbicide-polluted agricultural runoff resulted in a 69.4% remediation efficiency. Thus, the study demonstrated the valorization of date palm leaves into a valuable and industry-ready adsorbent that can sequester toxic 2,4-DPA herbicide contaminant from aqueous streams.

Phycoremediation for carbon neutrality and circular economy: Potential, trends, and challenges.

Phycoremediation is gaining attention not only as a pollutant mitigation approach but also as one of the most cost-effective paths to achieve carbon neutrality. When compared to conventional treatment methods, phycoremediation is highly effective in removing noxious substances from wastewater and is inexpensive, eco-friendly, abundantly available, and has many other advantages. The process results in valuable bioproducts and bioenergy sources combined with pollutants capture, sequestration, and utilization. In this review, microalgae-based phycoremediation of various wastewaters for carbon neutrality and circular economy is analyzed scientometrically. Different mechanisms for pollutants removal and resource recovery from wastewaters are explained. Further, critical parameters that influence the engineering design and phycoremediation performance are described. A comprehensive knowledge map highlighting the microalgae potential to treat a variety of industrial effluents is also presented. Finally, challenges and future prospects for industrial implementation of phycoremediation towards carbon neutrality coupled with circular economy are discussed.